Mathias Steglich, Yvain Carpentier, Cornelia Jäger, Friedrich Huisken, Hans-Joachim Räder, Thomas Henning
Context: As revealed by high-resolution spectral investigations in the wavelength range between 300 and 400 nm, the interstellar extinction curve does not display any sharp electronic absorption bands characteristic for large polyatomic molecules, like polycyclic aromatic hydrocarbons (PAHs), which belong to the most abundant interstellar molecules. Aims: We try to verify whether the absorption curves of mixtures of medium-sized PAHs produced in the laboratory can explain the astronomical observations. Methods: The PAH mixtures were synthesized by infrared laser pyrolysis and subsequent chemical extraction and size separation. The matrix isolation technique was used to study the absorption spectra of isolated molecules at low temperature. Results: Our experimental results demonstrate that the UV-visible absorption curves of PAH mixtures can be very smooth, displaying no sharp bands, if the molecular diversity is sufficiently high. Conclusions: In view of the absence of sharp electronic features on the interstellar extinction curve for 300 < lambda < 400 nm, we conclude from our experimental findings that the interstellar PAH population must be very diverse. The low fractional abundances of individual species prevent their detection on the basis of spectral fingerprints in the UV.
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http://arxiv.org/abs/1203.2026
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